| Tenure | Name | Title | Country |
|---|---|---|---|
| 2021 - 2024 | Adelardus Lubango Kilangi | Ambassador | Brazil |
| 2024 To Date | Dr. John Stephen Simbachawene | Ambassador | Brazil |
| 2008 - 2010 | Prof. Joram Mukama Biswaro | Ambassador | Brazil |
| 2011 - 2015 | Francis A. Malambugi | Ambassador | Brazil |
| 2016 - 2021 | Dr. Emmanuel John Nchimbi | Ambassador | Brazil |
| Tenure | Name | Title | Country |